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Champagne and Chili
Rich, meaty (or vegetarian) chili actually does quite well with champagne, as long as it's not too spicy. Champagne's acidic nature can tame heat to a certain extent, but you'll to avoid brut varieties, which lack the necessary sweetness to do so. If your chili is particularly tomato-y, champagne also helps counterbalance its acidity.
Champagne suggestion: Extra-dry
Here are some delicious twists on chili you've got to try.